高级检索

    电感耦合等离子体质谱法测定糜类制品中二氧化钛的含量

    Determination of Titanium Dioxide in Minced Products by ICP-MS

    • 摘要: 取糜类制品及其原料样品0.500 0 g,用硝酸5 mL和氢氟酸1 mL于200℃微波消解20 min,冷却至室温,用水定容至25.0 mL。采用电感耦合等离子体质谱法测定样品溶液中二氧化钛含量。结果表明:钛的线性范围为10~200 μg·L-1,检出限(3s)为0.06 mg·kg-1;对样品进行加标回收试验,回收率在88.0%~93.2%之间,相对标准偏差(n=6)在1.0%~3.7%之间。按所提出的方法分析了42批次原料及100批次糜类制品,发现样品中二氧化钛平均值分别约为2.5 mg·kg-1和5.0 mg·kg-1,有10%的糜类制品中二氧化钛测定值高于100 mg·kg-1,存在超范围使用二氧化钛的风险。

       

      Abstract: Sample of minced products (0.500 0 g) was digested in the mixture of 5 mL HNO3 and 1 mL HF using microwave, with heating at the temperature of 200℃ for 20 min, and then the solution was cooled to room temperature, and made its volume up to 25.0 mL. The content of titanium dioxide in above solution was determined by inductively coupled plasma mass spectrometry (ICP-MS). As shown by the results, linear relationship of Ti was found in the range of 10-200 μg·L-1, with detection limit (3s) of 0.06 mg·kg-1. Tests for recovery was made by standard addition method, giving results in the range of 88.0%-93.2%. Values of RSDs (n=6) were in the range of 1.0%-3.7%. 42 batches of raw materials and 100 batches of minced products were analyzed by the proposed method, and average contents of titanium dioxide were found about 2.5 mg·kg-1 and 5.0 mg·kg-1 respectively. The contents of titanium dioxide in 10% of minced products were higher than 100 mg·kg-1, and there was a risk of exceeding the range of use of titanium dioxide.

       

    /

    返回文章
    返回