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    二苯乙烯型荧光增白剂光降解及检测研究进展

    Research Progress in Photodegradation and Detection of Stilbene-Type Fluorescent Whitening Agents

    • 摘要: 二苯乙烯型荧光增白剂因荧光效率高和稳定性强等优点,在造纸、纺织、化妆品和洗涤剂等方面应用广泛。近年来,国内外关于荧光增白剂的污染和检验方法的报道逐渐增多,引起社会的高度关注。总结了目前对二苯乙烯型荧光增白剂光降解机理研究和利用光降解解决污染的方法。简要概述了加速溶剂萃取、凝胶色谱、固相萃取法和QuEChERS等前处理技术,汇总了我国目前关于荧光增白剂的标准检测方法,重点综述了紫外光谱法、荧光光谱法、液相色谱法、液相色谱-串联质谱法和便携式检测等检测技术在二苯乙烯型荧光增白剂中的应用,并对二苯乙烯型荧光增白剂在法庭科学的应用做出展望,同时为治理其污染提出了一些建议,为我国建立二苯乙烯型荧光增白剂现实可行的法规提供了一些思路(引用文献122篇)。

       

      Abstract: Stilbene-type fluorescent whitening agents are widely used in papermaking, textiles, cosmetics and detergents due to their advantages of high fluorescence efficiency and stability. In recent years, domestic and foreign reports on the contamination and testing methods of fluorescent whitening agents have gradually increased, causing great concern in the society. The current research on the mechanism of photodegradation of stilbene-type fluorescent whitening agents and the methods using photodegradation to solve the pollution were summarized. The pretreatment techniques such as accelerated solvent extraction, gel chromatography, solid phase extraction and QuEChERS were briefly summarized, and the current standard detection methods of fluorescent whitening agents in China were summarized. The application of detection technologies such as ultraviolet spectrometry, fluorescence spectrometry, liquid chromatography, liquid chromatography-tandem mass spectrometry and portable detection in the stilbene-type fluorescent whitening agents was emphatically reviewed. The application of stilbene-type fluorescent whitening agents in forensic science was prospected, and some suggestions were put forward to control its pollution, which provided some ideas for the establishment of practical and feasible laws and regulations on stilbene-type fluorescent whitening agents in China (122 ref. cited).

       

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