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    离子色谱-串联质谱法测定生活饮用水中草甘膦、氨甲基膦酸、高氯酸盐和5种消毒副产物的含量

    Determination of Glyphosate, Aminomethylphosphonic Acid, Perchlorate and 5 Disinfection By-Products in Drinking Water by Ion Chromatography-Tandem Mass Spectrometry

    • 摘要: 为实现生活饮用水中草甘膦(GLY)、氨甲基膦酸、高氯酸盐(ClO4)和5种消毒副产物二氯乙酸、三氯乙酸(TCAA)、溴酸盐(BrO3)、亚氯酸盐、氯酸盐(ClO3)的绿色、快速、高灵敏同时检测,进行了题示研究。生活饮用水样经0.22 μm聚醚砜(PES)滤膜过滤后,滤液直接进入离子色谱-串联质谱仪,8种目标物在Ionpac AS20阴离子分析柱上采用由在线淋洗液发生器产生的氢氧化钾溶液进行梯度洗脱分离,在电喷雾离子源负离子模式下电离,以多反应监测模式检测,外标法定量。结果显示,8种目标物的质量浓度在一定范围和对应的峰面积呈线性关系,检出限为0.05~1.0 μg·L−1。按照标准加入法进行回收试验,回收率为71.1%~115%,测定值的相对标准偏差(n=6)为1.1%~6.5%。方法用于61份生活饮用水的分析,检出了ClO4、ClO3、BrO3、TCAA、GLY,检出量为0.6~38.5 μg·L−1

       

      Abstract: To achieve green, rapid, and highly sensitive simultaneous detection of glyphosate (GLY), aminomethylphosphonic acid, perchlorate (ClO4), and 5 disinfection by-products dichloroacetic acid, trichloroacetic acid (TCAA), bromate (BrO3), chlorite, and chlorate (ClO3) in drinking water, the study mentioned by the title was conducted. The drinking water samples were passed through a 0.22 μm polyethersulfone (PES) filter membrane, and the filtrate was directly introduced into the ion chromatograph-tandem mass spectrometer. The 8 target compounds were separated on Ionpac AS20 anion analytical column by gradient elution using the potassium hydroxide solution generated by an online eluent generator, ionized in negative ion mode with electrospray ionization source, detected by multiple reaction monitoring, and quantified by external standard method. It was shown that linear relationships between the mass concentrations of the 8 target compounds and their corresponding peak areas were kept in definite ranges, with detection limits in the range of 0.05-1.0 μg · L−1. Test for recovery was made using standard addition method, giving recoveries in the range of 71.1%-115%, and RSDs (n=6) of the determined values ranged from 1.1% to 6.5%. The proposed method was applied to the analysis of 61 drinking water samples, and ClO4, ClO3, BrO3, TCAA, and GLY were detected at detection amounts in the range of 0.6-38.5 μg · L−1.

       

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