基于差示扫描量热法的火工品材料选型研究
Study on Pyrotechnics Material Selection Based on Differential Scanning Calorimeter
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摘要: 通过综合分析差示扫描量热法(DSC)图谱及动力学数据,进行火工品中药剂外包覆材料的选型研究。采用DSC测试炸药与不同涂敷层材料在不同升温速率的热性质,利用Ozawa法和DSC曲线对比法,对几种涂敷层材料进行分析。炸药与丙烯酸清漆混合后,DSC曲线表观性征、峰温以及反应的活化能变化最小;炸药与快速固化剂混合后,峰温及活化能变化影响居中,DSC曲线表观性征在升温速率大时有较大变化;炸药与硅橡胶混合后,DSC曲线表观性征、峰温以及反应的活化能变化最大。从而确定丙烯酸清漆为最合适的炸药包覆材料。Abstract: Here we studied on the selection of external pyrotechnics pharmaceutical coating material by a comprehensive analysis of the diagrams of differential scanning calorimetry (DSC) and the kinetics. DSC was used to study thermal properties of explosives mixed with different coating materials at different heating rates. The Ozawa method and DSC curve comparison method were used to examine the coating materials. The changes of DSC curve characterization, peak temperature and apparent activation energy were the smallest when the explosive was mixed with acrylic varnish, while the changes were modest when it was mixed with rapid hardener with significant changes on the DSC curve at the higher heating rate. The largest changes occurred when the explosive was mixed with silicone rubber. It was concluded that acrylic varnish was the most suitable coating material for that explosive.