Abstract: Residual pesticides in vegetables were extracted with ethyl acetate and purified by passing the extract through a gel permeation chromatographic column.Elute the column with cyclohexane-ethyl acetate (1∶1,V/V) at a flow rate of 5 mL·min-1 and collect the fractions between 85-175 mL.Concentrate the collected eluate to dryness and dissolve it with 1 mL of cyclohexane-ethyl acetate.The residual pesticides were detected with a capillary gas chromatograph equipped with nitrogen-phosphorus detector.Using the established three steps-heating program,23 peaks of pesticides were resolved.Detection limits of the proposed method were in the range of 0.002-0.005 mg·kg-1,and linearity relationship between 0.5-5.0 mg·L-1 was obtained.Recovery was ranged in 75.6%-110.7% and RSDs of determination were ranged in 0.56%-8.26%.The method has been applied to the analysis of the residual pesticides in vegetables and fruits.