Abstract: Residual amounts of organophosphorus pesticides in samples of tobacoo were dispersed by matrix sold phase dispersion technique,and eluted with acetone. The extract obtained was concentrated and made up to 1 mL,the solution in acetone was used for GC determination. By using the HP-5 capillary chromatofraphic column,5 organophosphorus pesticides were separated and determinaed by PFPD. The values of detection limit (3S/N) found were in the range of 0.02-0.04 μg·g-1. Precision and recovery of the method were tested,and values of RSD′s (n=5) and of recovery found were in the ranges of 1.1%-3.6% and 89.85%-102.66% respectively.