Abstract: A review on the application of various types of chiral stationary phase to capillary electrochro-matographic separation of enantiomers in drug analysis,including chiral stationary phases (CSP) of amylose derivatives,protein,macrocylic compounds,prikles,ligand-exchanges,and molecular inprinted polymers (MIP) as well as the mechanism involved in the separations was given in this paper (62 ref.cited).